The behavior of iron and zinc stable isotopes accompanying the subduction of mafic oceanic crust: A case study from Western Alpine ophiolites
Résumé
Arc lavas display elevated Fe31/RFe ratios relative to MORB. One mechanism to explain this is
the mobilization and transfer of oxidized or oxidizing components from the subducting slab to the mantle
wedge. Here we use iron and zinc isotopes, which are fractionated upon complexation by sulfide, chloride,
and carbonate ligands, to remark on the chemistry and oxidation state of fluids released during prograde
metamorphism of subducted oceanic crust. We present data for metagabbros and metabasalts from the
Chenaillet massif, Queyras complex, and the Zermatt-Saas ophiolite (Western European Alps), which have
been metamorphosed at typical subduction zone P-T conditions and preserve their prograde metamorphic
history. There is no systematic, detectable fractionation of either Fe or Zn isotopes across metamorphic
facies, rather the isotope composition of the eclogites overlaps with published data for MORB. The lack of
resolvable Fe isotope fractionation with increasing prograde metamorphism likely reflects the mass balance
of the system, and in this scenario Fe mobility is not traceable with Fe isotopes. Given that Zn isotopes are
fractionated by S-bearing and C-bearing fluids, this suggests that relatively small amounts of Zn are mobilized
from the mafic lithologies in within these types of dehydration fluids. Conversely, metagabbros from
the Queyras that are in proximity to metasediments display a significant Fe isotope fractionation. The
covariation of d56Fe of these samples with selected fluid mobile elements suggests the infiltration of sediment
derived fluids with an isotopically light signature during subduction.
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