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Article Dans Une Revue Synthetic Metals Année : 1996

Thermodynamics of intercalation in C60 fullerite and stability of cubic close-packed fulleride compounds

Daniel Claves
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Ph. Touzain
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Résumé

Stability of known or hypothetical fullerene C60 intercalation compounds was investigated through a donnor-acceptor scheme. A thermodynamical cycle was employed, requiring evaluation of energy costs related with charge transfer and formation of the intercalated solid. Strongly exothermic reactions are predicted in several cases, especially with some elements of the rare-earths series, which should consequently form stable low dimensional phases. These latter might be interesting candidates for superconductivity, as alkali-doped C60.

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Chimie
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Dates et versions

hal-04051262 , version 1 (30-05-2023)

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  • HAL Id : hal-04051262 , version 1

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Daniel Claves, Ph. Touzain. Thermodynamics of intercalation in C60 fullerite and stability of cubic close-packed fulleride compounds. Synthetic Metals, 1996, 80, pp.301-307. ⟨hal-04051262⟩
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