Arylopeptoid oligomers functionalised by combinatorial or sequential on-resin click chemistry using a copper(I)–N-heterocyclic carbene catalyst - Université Clermont Auvergne Accéder directement au contenu
Article Dans Une Revue Organic & Biomolecular Chemistry Année : 2022

Arylopeptoid oligomers functionalised by combinatorial or sequential on-resin click chemistry using a copper(I)–N-heterocyclic carbene catalyst

Résumé

An efficient on-resin click chemistry protocol using a stable copper(I)–N-heterocyclic carbene catalyst is developed for post-functionalization of N-alkylated aminomethylbenzamide oligomers (arylopeptoids). The accessibility to a panel of polyfunctionalized N-substituted aromatic oligoamides by solid-phase synthesis is demonstrated using combinatorial and sequential approaches.

Domaines

Chimie
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Dates et versions

hal-03762807 , version 1 (06-11-2022)

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Citer

Ayman Akhdar, Sophie Faure, Arnaud Gautier. Arylopeptoid oligomers functionalised by combinatorial or sequential on-resin click chemistry using a copper(I)–N-heterocyclic carbene catalyst. Organic & Biomolecular Chemistry, 2022, 20 (12), pp.2402-2406. ⟨10.1039/d2ob00163b⟩. ⟨hal-03762807⟩
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