Reliability study under thermal and photonic stresses of sulforhodamine B (SRB) confined in layered double hydroxide (LDH) - Université Clermont Auvergne Accéder directement au contenu
Article Dans Une Revue Applied Clay Science Année : 2020

Reliability study under thermal and photonic stresses of sulforhodamine B (SRB) confined in layered double hydroxide (LDH)

Fabrice Leroux
Sandrine Therias
Damien Boyer
François Réveret

Résumé

When sulforhodamine B (SRB) is entrapped in a tightly packed hybrid material composed of dodecylsulfate anions interleaved in layered double hydroxide, the organic dye is considered as a possible red-emitting phosphor for white light-emitting diodes (WLEDs). To confirm such promising potential, a reliability study is here undertaken and the materials and their associated silicone films are subjected to different thermal and photonic stresses. Optical properties, photoluminescence quantum yields and emission spectra are recorded after photo-aging studies. Interestingly, the composite silicone film is found to be completely stable under blue LED excitation, while in the absence of the hybrid LDH the emission of SRB decays rapidly, thus underlining the protective role of the LDH hybrid cargo. At this stage, these results confirm the potential offered by a system consisting of such an emitter film and a blue LED. This system also opens up new possibilities for interesting organic dyes that are sensitive to photonic and/or thermal stresses.

Domaines

Matériaux
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Dates et versions

hal-03016985 , version 1 (20-11-2020)

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Paul Legentil, Fabrice Leroux, Sandrine Therias, Damien Boyer, François Réveret, et al.. Reliability study under thermal and photonic stresses of sulforhodamine B (SRB) confined in layered double hydroxide (LDH). Applied Clay Science, 2020, pp.105922. ⟨10.1016/j.clay.2020.105922⟩. ⟨hal-03016985⟩
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